Bluefish, thanks for your reply.
I certainly can't rule out stratification, but after 5 days in the tank I'd have thought all of the distribution of wort that was going to happen would have happened already!
It's also important to note the gravity didn't change from 1.011 in the days after, so it's safe to assume the batch was no longer actively fermenting on day 6.
Does anyone have any thoughts on my 'secondary conversion' hypothesis?