If you want to know more about the dunder/muck pits you will have to dig deep into the innerweb vaults and read between the lines. i started my journey by reading "the great dunder thread" on the still dragon forum. there ia a lot on information there on why we use the dunder. a quick understanding on the is it makes more flavour. how it does that is a bio-chemists dreams/nightmare. being the rum junky i am, I'm chasing an old style Jamaican with lots of funk. the funk is created with dunder. basically how this works is there are lots of unfermentables in the rum wash. that is because the yeast can't break them down. this is where the yeasts dodgy cousin comes in A.K.A Bacteria! (i say cousin but that only because they are both little organisms, please don't shoot me). these guys now go about their dirty business of breaking down the unfermatables and creating the lovely esters we want in our funky rum. that's what the funk is, a high ester rum. what are esters? these are the chemical compounds that our tongues interpret as flavour. there are whole ester charts and what compound make them. all i know is that if your wash smells like vomit you have probably got lots of butanic acid. when this ages with the alcohols you gonna get that lovely pineapple note coming through.
i have attached a file of some of the ester charts i have found.