We've done some whiskey from 100% unmalted barley flour, we just mashed it the same as how we deal with other unmalted grains using a high temp alpha and gluco. So far the unmalted barley spirit has gotten pretty poor marks for flavor, and we'll ultimately probably need to blend the barrels with something else down the road. We've tried out a lot of different grains (rice, oats, rye, wheat, corn, millet, sorghum, barley) and unmalted barley is the least appealing to my palate.